[1-(1H-Imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol-κ2 N 7,N 8]diiodidomercury(II)
نویسنده
چکیده
In the title compound, [HgI(2)(C(23)H(14)N(4)O)], the Hg(II) atom is four-coordinated by two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol ligand and by two I atoms in a distorted tetra-hedral environment. An intra-molecular O-H⋯N hydrogen bond stabilizes the mol-ecular conformation and an inter-molecular N-H⋯I inter-action stabilizes the crystal packing.
منابع مشابه
Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water mol-ecule on a general position. Each Cd(II) cation is six-coordinated by the two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (L) ligand an...
متن کاملDi-μ-sulfato-κ4 O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2 N 7,N 9)cobalt(II)] dihydrate
In the centrosymmetric dinuclear title compound, [Co(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) atom is coord-in-ated by two N atoms from two 1H-imidazo[4,5-f][1,10]phenanthroline ligands, two O atoms from two sulfate anions and two O atoms from water mol-ecules in a distorted octa-hedral geometry. The Co⋯Co separation is 5.1167 (7) Å. The coordinated and uncoordinated water m...
متن کاملPoly[(μ3-biphenyl-3,4′-dicarboxylato-κ4 O 3:O 3′:O 4′,O 4′′)(1H-imidazo[4,5-f][1,10]phenanthroline-κ2 N 7,N 8)manganese(II)]
In the title compound, [Mn(C(14)H(8)O(4))(C(13)H(8)N(4))](n), the Mn(II) atom is six-coordinated in a distorted octa-hedral geometry by four O atoms from three different carboxyl-ate groups and two N atoms from one imidazo[4,5-f][1,10]phenanthroline mol-ecule. The organic ligands link inorganic Mn(II) nodes, forming a zigzag chain along the c axis.
متن کامل1-(1H-Imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol
In the title mol-ecule, C(23)H(14)N(4)O, the dihedral angle between the pyridine rings of the phenanthroline unit is 4.43 (8)° and the dihedral angle formed by the nine essentially planar [maximum deviation 0.0389 (16)Å] non-H atoms of the benzimidazole unit and the naphthalene ring system is 74.22 (5)°. In the crystal, mol-ecules are linked by inter-molecular N-H⋯N and O-H⋯N hydrogen bonds, fo...
متن کاملCrystal structure of a binuclear nickel(II) complex constructed of 1H-imidazo[4,5-f][1,10]phenanthroline and doubly deprotonated benzene-1,3,5-tricarboxylic acid
The title complex, [Ni2(C9H4O6)2(C13H8N4)2(H2O)4]·2H2O, bis-(μ-5-carb-oxy-benzene-1,3-di-carboxyl-ato-κ(2) O (1):O (1'))bis-[di-aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (8))nickel(II)] di-hydrate, was obtained under solvothermal conditions by the reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with Ni(NO3)2 in the presence of 1H-imidazo[4,5-f][1,10]phenanthroline (IP). The c...
متن کامل